CHEBI:69116 - withalongolide L

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ChEBI Name withalongolide L
ChEBI ID CHEBI:69116
Definition A steroid saponin that is the monosaccharide derivative of the 19-norwithanolide. It has been isolated from the aerial parts of Physalis longifolia.
Stars This entity has been manually annotated by the ChEBI Team.
Supplier Information
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Formula C33H48O11
Net Charge 0
Average Mass 620.72760
Monoisotopic Mass 620.31966
InChI InChI=1S/C33H48O11/c1-14-16(13-42-32-30(40)29(39)28(38)26(12-34)44-32)8-25(43-31(14)41)15(2)21-4-5-22-19-11-23(36)20-9-17(35)10-24(37)27(20)18(19)6-7-33(21,22)3/h15,17-19,21-23,25-26,28-30,32,34-36,38-40H,4-13H2,1-3H3/t15-,17+,18-,19+,21+,22-,23-,25+,26+,28+,29-,30+,32+,33+/m0/s1
InChIKey DKRAEDZNHJHJAB-YJKJOOOHSA-N
SMILES C[C@@H]([C@H]1CC[C@H]2[C@@H]3C[C@H](O)C4=C([C@H]3CC[C@]12C)C(=O)C[C@H](O)C4)[C@H]1CC(CO[C@@H]2O[C@H](CO)[C@@H](O)[C@H](O)[C@H]2O)=C(C)C(=O)O1
Metabolite of Species Details
Physalis longifolia (NCBI:txid161495) Found in aerial part (BTO:0001658). CH2Cl2-MeOH(1:1) extract of the air-dried aerial parts See: PubMed
Roles Classification
Biological Role(s): metabolite
Any intermediate or product resulting from metabolism. The term 'metabolite' subsumes the classes commonly known as primary and secondary metabolites.
(via saponin )
plant metabolite
Any eukaryotic metabolite produced during a metabolic reaction in plants, the kingdom that include flowering plants, conifers and other gymnosperms.
View more via ChEBI Ontology
ChEBI Ontology
Outgoing withalongolide L (CHEBI:69116) has role metabolite (CHEBI:25212)
withalongolide L (CHEBI:69116) has role plant metabolite (CHEBI:76924)
withalongolide L (CHEBI:69116) is a β-D-glucoside (CHEBI:22798)
withalongolide L (CHEBI:69116) is a δ-lactone (CHEBI:18946)
withalongolide L (CHEBI:69116) is a 3β-hydroxy steroid (CHEBI:36836)
withalongolide L (CHEBI:69116) is a 6α-hydroxy steroid (CHEBI:36850)
withalongolide L (CHEBI:69116) is a monosaccharide derivative (CHEBI:63367)
withalongolide L (CHEBI:69116) is a steroid saponin (CHEBI:61655)
IUPAC Name
[(2R)-2-{(1S)-1-[(3β,6α,17β)-3,6-dihydroxy-1-oxoestr-5(10)-en-17-yl]ethyl}-5-methyl-6-oxo-3,6-dihydro-2H-pyran-4-yl]methyl β-D-glucopyranoside
Synonym Source
28-O-β-D-glucopyranosyl-3β,6α-dihydroxy-1-oxo-19-norwitha-5(10),24-dienolide ChEBI
Registry Number Type Source
22217720 Reaxys Registry Number Reaxys
Citation Waiting for Citations Type Source
22098611 PubMed citation Europe PMC
Last Modified
20 November 2013