Term Information

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Accession
GO:0018684
Name
2,5-diketocamphane 1,2-monooxygenase
Ontology
molecular_function
Synonyms
camphor 1,2-monooxygenase activity, (+)-camphor,reduced-rubredoxin:oxygen oxidoreductase (1,2-lactonizing), 2,5-diketocamphane lactonizing enzyme activity, camphor ketolactonase I activity
Alternate IDs
None
Definition
Catalysis of the reaction: 1R,4R)-bornane-2,5-dione + FMNH2 + O2 = (1R,4R)-5-oxo-1,2-campholide + FMN + H+ + H2O. Source: PMID:3944058, RHEA:34415, PMID:8515237
Comment
Formerly EC:1.14.15.2.
History
See term history for GO:0018684 at QuickGO
Chem. react.
has participant FMNH2(2-)
has participant (1R)-bornane-2,5-dione
has participant (-)-5-oxo-1,2-campholide
has participant hydron
has participant water
has participant dioxygen
has participant FMN(3-)
Subset
None
Include "regulates"
For more information, please see the ontology relation documentation.

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Parents of 2,5-diketocamphane 1,2-monooxygenase (GO:0018684)
subject[Reorder by subject] relation[Reorder by relation] object[Reorder by object]
2,5-diketocamphane 1,2-monooxygenase [RO:0000057 relation] RO:0000057  FMNH2(2-) (CHEBI:57618)
2,5-diketocamphane 1,2-monooxygenase [RO:0000057 relation] RO:0000057  (1R)-bornane-2,5-dione (CHEBI:15392)
2,5-diketocamphane 1,2-monooxygenase [is_a relation] is_a  oxidoreductase activity, acting on paired donors, with incorporation or reduction of molecular oxygen, reduced flavin or flavoprotein as one donor, and incorporation of one atom of oxygen (GO:0016712)
2,5-diketocamphane 1,2-monooxygenase [RO:0000057 relation] RO:0000057  (-)-5-oxo-1,2-campholide (CHEBI:18130)
2,5-diketocamphane 1,2-monooxygenase [RO:0000057 relation] RO:0000057  hydron (CHEBI:15378)
2,5-diketocamphane 1,2-monooxygenase [RO:0000057 relation] RO:0000057  water (CHEBI:15377)
2,5-diketocamphane 1,2-monooxygenase [RO:0000057 relation] RO:0000057  dioxygen (CHEBI:15379)
2,5-diketocamphane 1,2-monooxygenase [RO:0000057 relation] RO:0000057  FMN(3-) (CHEBI:58210)

This term has no children.

EC
1.14.14.108
MetaCyc
R543-RXN
RHEA
34415
UM-BBD_enzymeID
e0302